We find a wide range of ground state conformations, including a coil, a globule, a toroid, rods, helices, and zig-zag strands resembling β-sheets, as well as knotted conformations allowing us to bridge conventional polymer phases and biomolecular phases. Using detailed Wang-Landau microcanonical Monte Carlo simulations, we study the interplay between the nature of the stiffness and the ground state conformation of a self-attracting chain. We consider three types of stiffnesses-one yielding an energy penalty for local bends (energetic stiffness) and the other two forbidding certain classes of chain conformations (entropic stiffness). Our focus here is on distinct ways of modeling the stiffness inherent in a chain molecule.
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